The short story is that if you have a standard configuration things should work entirely as you’d expect. That is, download the archive which, these days, comes as a RedHat “rpm” file. Become “root” and enter “rpm -ivh oracle-xe.rpm” and wait a bit. The install goes away and creates all the required users, starts up the listener and creates a default empty database.
CentOS, for those that have not come across it, is a Linux operating system built from the same source package as RedHat Enterprise Linux but without the support contract.